The biggest problem with JBoss is the complete lack of documentation, so when it comes to learning, you are basically on your own.
Really, the Admin guide is right there at jboss.org.
Anyway, JBoss is really simple that to start-off you don't need any documentations.
Here is what you need to know.
In Jboss there is a bin directory, in it has a run.bat or run.sh use it to start up your App Server.
In this case it runs the "default" server So in the server/default/deploy directory is where you copy you archive files to deploy. If you want expanded, juut create a directory with the name of the archive you would have created if you created one, and copy your classes there.
So know you can run anything. And that is the only JBoss specific stuff you would need that is different than what you would need to know with Sun's App Server.
Also note, that even though I had this opinion for 6 years, I work for JBoss, started 2 months ago.
Mark