b)Reliability
As I see it, scalability is the capability of a system to handle a growing amount of loading provided with additional resources, while the reliability will assure the system still respond correctly when under heavy load.
Now, adding more servers to your system is something made possible by the scalability attribute of your system but will not increase the attribute. It will just
scale the system.
On the other hand, adding more server could indeed help with reliability of your system if not from else at least because it just unload it.
So, the bottom-line: improved scalability is an enabler for adding more servers and reliability is a consequence of it.
Probably, I got it all wrong.