I'm not familiar with Apache Httpd set-up, but one thing I'd change is to make sure your '/' and '\' are consistent. Since you are not using spaces in your directory paths
you should be able to use '\' safely. To also identify the root cause of the problem a little easier, I'd recommend having website one as separate from the default, e.g. Have:
Httpd.conf - setup
My httpd-vhosts.conf -Setup
This might help identify a problem where the DocumentRoot isn't being overridden as you'd expect.