Yes, both are same.
As of September 1 2010, Sun certifications have been republished and re-branded under the Oracle certification program.
Oracle Certified Professional, Java EE 5 Web Services Developer (Formerly Sun Certified Web Services Developer (SCDJWS 5)) certification provides knowledge required to develop Java EE 5 Web service applications using JAX-WS and XML processing APIs.
You need to complete 1Z0-862 Java Enterprise Edition 5 Web Services Developer Certified Professional Exam to achieve this certification.
Read more about OCPJDWS 5 here =>
http://www.epractizelabs.com/blog2/?p=145