So a Table level constraint might be that two fields that have dates, lets say, and you want to make sure that the start_date is prior to the end_date, that is where only a table level contraint will work. You cannot create a column level constraint that compares to some other column.
With Null, null is a value you can put in a field, you can't put a null into a table. meaning you can't set a table to equal null.
HTH
Mark